Photochemical transformations of divinyl arenes
نویسندگان
چکیده
منابع مشابه
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2 1. Introduction Photochemistry of the porphyrins and their relatives has been largely inspired by photosynthetic processes in nature. As a result of this, most current studies generally utilize the chemistry of magnesium and zinc porphyrin analogues. Especially, magnesium tetrapyrrole chelates, i.e. magnesium porphyrins and phthalocyanines have found wide interest. This is primarily related t...
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1,1-Divinyl-2-phenylcyclopropanes are entry points to a rich area of rearrangement chemistry. With N,N-diallyl amide substrates, tandem radical cyclizations can be initiated at room temperature. Warming provides products of pure thermal rearrangements with acids, ester, and amides. These isomerizations give vinylcyclopentenes resulting from divinylcyclopropane rearrangements and more deeply rea...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 1970
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac197024030509